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Reference · Formulas

Chemistry Formulas

A copy-able sheet — moles, gas laws, solutions, thermochemistry, equilibrium, acids, kinetics, and cells.

Showing 49 of 49. Click any formula to copy it.

Every temperature in these equations is absolute: convert °C to kelvin by adding 273.15 before substituting. The gas constant takes the value matching your pressure units — 0.08206 L·atm/(mol·K) for PV = nRT in atmospheres, 8.314 J/(mol·K) for energy work.

Almost every chemistry calculation passes through the mole. n = m ÷ M converts a mass to moles, the balanced equation converts moles of one substance to another, and n = m ÷ M runs backwards to give the answer as a mass. The sheet above groups the rest by topic.

The mole sits in the middle of everything

Balanced equations are written in moles, but nothing in a laboratory is measured in them — you weigh grams, pipette millilitres, read a pressure. So the shape of a stoichiometry problem is always the same three steps: convert what you measured into moles, use the coefficients of the balanced equation to cross to the substance you care about, then convert back into whatever unit the question wants.

Which conversion you use depends only on what you were given. A mass goes through n = m ÷ M. A gas volume goes through the ideal gas law. A solution goes through molarity, moles = M × V. All three arrive at the same place, and once you are in moles the rest of the problem is the ratio from the equation.

Enthalpy, entropy, and what actually decides a reaction

ΔH tells you whether a reaction releases or absorbs heat, but not whether it happens. ΔG = ΔH − TΔS is what decides: a reaction is spontaneous when ΔG is negative. Because temperature multiplies the entropy term, a reaction that is not spontaneous when cold can become so when hot — which is why the T in that formula must be in kelvin.

Choosing the conversion into moles

What you were given decides the route; the balanced equation then carries you to the substance you want.

You are givenUseTo get
A mass in gramsn = m ÷ MMoles of that substance
A gas volume, pressure, temperaturen = PV ÷ RTMoles of gas
A solution volume and molarityn = M × VMoles of solute
A particle countn = N ÷ NₐMoles of particles
Moles of one reactantcoefficient ratioMoles of any other species

What the sign of ΔG means

ΔG = ΔH − TΔS, with T in kelvin. Spontaneous does not mean fast — that is kinetics, not thermodynamics.

ΔHΔSSpontaneous when
Negative (exothermic)PositiveAlways, at every temperature
Negative (exothermic)NegativeAt low temperature
Positive (endothermic)PositiveAt high temperature
Positive (endothermic)NegativeNever, at any temperature

The errors that ruin an otherwise correct answer

Temperature is the big one. Every gas law, the Gibbs equation, and the Arrhenius equation need absolute temperature, so °C must become kelvin by adding 273.15 before substituting. A gas law worked in Celsius does not fail loudly — it just returns a confidently wrong number.

The gas constant is the second. R takes different values in different unit systems: 0.08206 L·atm/(mol·K) for PV = nRT with pressure in atmospheres, and 8.314 J/(mol·K) when the answer is an energy, as in the Arrhenius and Nernst equations. Pick the one matching your units. Third, a limiting-reagent problem must be tested reagent by reagent — converting only the reactant named first in the question is the most common way to lose the whole calculation.

Why does almost every chemistry problem convert to moles first?
Balanced equations relate substances in mole ratios, not grams or litres. Converting your measurement into moles is what lets the coefficients do their job; converting back at the end returns the answer in the unit the question asked for.
Which value of R should I use?
Use 0.08206 L·atm/(mol·K) for PV = nRT with pressure in atmospheres and volume in litres. Use 8.314 J/(mol·K) whenever the result is an energy, such as in ΔG° = −RT ln K or the Arrhenius equation.
What is the difference between molarity and molality?
Molarity is moles of solute per litre of solution and depends on temperature, since volume expands. Molality is moles per kilogram of solvent and does not, which is why the colligative formulas for boiling and freezing points use molality.
How do I know whether a reaction is spontaneous?
Compute ΔG = ΔH − TΔS with T in kelvin: negative ΔG means spontaneous. Note that spontaneous says nothing about speed — a reaction can have a strongly negative ΔG and still take years without a catalyst.
What does the van ’t Hoff factor i do in the colligative formulas?
It counts the particles a solute breaks into. Sugar stays as one particle so i = 1, NaCl dissociates into two ions so i ≈ 2, and CaCl₂ into three so i ≈ 3. Ignoring it underestimates the freezing point depression.
How do I find the limiting reagent?
Convert every reactant to moles, divide each by its coefficient in the balanced equation, and the smallest result is the limiting reagent. It sets the theoretical yield; the others are in excess.
Why is pH + pOH equal to 14?
Because the ion product of water K_w = [H₃O⁺][OH⁻] is 1.0×10⁻¹⁴ at 25 °C, and taking negative logarithms turns that product into a sum. The value shifts at other temperatures, since K_w itself is temperature-dependent.